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Magnet Sales
Unit 31,
Blackworth Industrial Estate,
Highworth,
Swindon,
UK,
SN6 7NA.
Registered in England 2858057
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WHICH MATERIAL ?
Several characteristics have to be taken into consideration when deciding which permanent magnetic material to use. These are: -
- Flux requirement for the particular application.
- Maximum operating temperature.
- Cost.
- Availability.
- Degree of corrosion likely to be encountered.
- Magnetic stability required.
- Size and/or weight limitations.
Although there are many different types of permanent magnet material the following information considers only the four major types in use today. These are Alnico, Ferrite, Samarium Cobalt (SmCo) and Neodymium-Iron Boron (NdFeB). The individual grades within each type will be considered separately.
Most of the materials supplied are classed as Anisotropic, that is a preferred magnetic axis is determined during manufacturer and so the magnets can only be magnetised in that predetermined direction. Isotropic material may be magnetized in any direction, but are generally lower in performance than the Anisotropic grades.
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COMPARISON OF MAGNETIC PERFORMANCES
The
most convenient method of comparing the magnetic performance of
different types and grades of permanent magnet is to consider their
maximum energy product (BHmax). This is the point where the magnet will
provide most energy for the minimum volume, so:-
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MGO
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kJ/m3
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Ferrite (anisotropic)
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3.3
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26
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Alnico (anisotropic Alcomax III)
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5.2
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42
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Samarium Cobalt 2:17)
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26
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208
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Neodymium-Iron-Boron (N38H)
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38
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306
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MGO in CGS units, kJ/m3 in SI units
It
is frequently necessary to know what flux density will be on the pole
face of a magnet. Often this is erroneously thought to be the Remanence
(Br), but this figure is purely the induction in a closed circuit
conditions and bears little relationship to the actual flux density
under normal working conditions.
The following table shows typical pole face flux densities for the four grades when working at approximately their BHmax points.
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Ferrite (anisotropic)
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100 mT (1000 Gauss)
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Alnico (anisotropic Alcomax III)
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130 mT (1300 Gauss)
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Samarium Cobalt 2:17)
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350 mT (3500 Gauss)
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Neodymium-Iron-Boron (N38H)
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450 mT (4500 Gauss)
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TEMPERATURE EFFECTS
These are in two distinct categories, reversible and irreversible. The
reversible changes with temperature, are dependant upon material
composition and are unaffected by the shape, size or the working point
on the demagnetisation curve. These types of losses disappear
completely without need for remagnetisation when the magnet is returned
to its initial temperature, whereas irreversible losses do not come
into operation until a certain temperature has been exceeded. These
types of losses can also be limited by operating at as high a working
point as possible. There are unrecoverable losses caused when excessive
temperatures are reached and metallurgical changes occur within magnet.
REVERSIBLE EFFECT OF TEMPERATURE (20C - 150 C)
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Ferrite (anisotropic)
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- 0.19% ºC
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Alnico (anisotropic Alcomax III)
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- 0.02% ºC
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Samarium Cobalt 2:17)
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- 0.03% ºC
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Neodymium-Iron-Boron (N38H)
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- 0.12% ºC
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MAXIMUM WORKING TEMPERATURES (BEFORE IRREVERSIBLE LOSSES COMMENCE)
The
maximum working temperature is dependant on the working point of the
magnet in the circuit. The higher the working point the higher the
temperature the magnet can operate
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Ferrite (anisotropic)
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250 ºC
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Alnico (anisotropic Alcomax III)
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550 ºC
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Samarium Cobalt 2:17)
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300 ºC
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Neodymium-Iron-Boron (N38H)
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120 ºC
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N.B. Irreversible losses may be restored by remagnetising the magnet
UNRECOVERABLE LOSSES (CURIE TEMPERATURE)
Each
material has a maximum temperature where metallurgical changes occur
within the magnet structure and where the individual magnetic domains
breakdown. Once these losses occur they cannot be reversed by
remagnetising.
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Ferrite (anisotropic)
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460 ºC
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Alnico (anisotropic Alcomax III)
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860 ºC
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Samarium Cobalt 2:17)
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750 ºC
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Neodymium-Iron-Boron (N38H)
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320 ºC
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EFFECTS OF SUB-ZERO TEMPERATURES
The effects of
low temperatures are different for each material group and are heavily
related to the magnet shape and therefore the its working point on its
demagnetization curve.
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Ferrite (anisotropic)
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Large irreversible losses below - 60 ºC
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Alnico (anisotropic Alcomax III)
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Permanent losses of no more than 10% are to be expected down to 4K
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Samarium Cobalt 2:17)
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Minimal losses down to 4K
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Neodymium-Iron-Boron (N38H)
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No irreversible losses down to 77K
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MAGNETIC STABILITY
The effect of temperature has the largest effect on magnet stability,
but exposure to high external fields can influence certain types of
magnets with the following degree of effect: -
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Ferrite (anisotropic)
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Low
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Alnico (anisotropic Alcomax III)
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High
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Samarium Cobalt 2:17)
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Very Low
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Neodymium-Iron-Boron (N38H)
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Very Low
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TIME
The effect of time on magnets is negligible
and averages a loss of less than 1 x 10-5 per annum at 20 oC. In a
100,000 hour period (11.4 years), these losses range from essentially
zero for SmCo to less than 3% for Alcomax III at low permeance
coefficients.
SHOCK & VIBRATION
Shock
and vibration was always an issue with our earliest magnets but for
modern magnet materials this is no longer a problem, apart from the
most closely calibrated devices.However, magnet materials may be
brittle and subject to fracture from mechanical impact (SmCo being the
most brittle).
RADIATION
Magnets are
used within particle beam deflection applications and it is recommended
that magnets with a higher Hci are used in such environments. Tests
have shown that SmCo displays significant losses when exposed to high
levels of radiation (109 to 1010 rads) and NdFeB losses 50 % at 4 x 106
rads and 100% at 7 x107 rads. At low levels of radiation, losses are in
line with that of temperature looses. Note that some magnet materials
contain Cobalt, which can retain radiation after exposure.
SHAPE
Magnet
shape does have an effect on performance and therefore its stability.
The shape of the magnet determines its working point along the
demagnetization curve. Higher up the curve the magnet operates, the
closer it is to its optimum working point and is therefore less
susceptible to external influences. Magnets used in a closed magnetic
circuit or with a longer length, perform better and are magnetically
more stable.
It is possible to help magnetic stability in
performance, by exposing the magnet in advance to any possible
detrimental influences by thermal cycling and controlled demagnetizing
fields (ageing) techniques.
Another cause of loss of
performance is the total breakdown of composition due to environmental
effects causing structural breakdown, such as corrosion or in the case
of NdFeB, exposure to Hydrogen.
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CORROSION RESISTANCE WHEN UNPROTECTED
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Ferrite (anisotropic)
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Excellent
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Alnico (anisotropic Alcomax III)
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Fair
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Samarium Cobalt 2:17)
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Excellent
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Neodymium-Iron-Boron (N38H)
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Poor
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There
are many protective coatings available and commonly used to help
prevent corrosion in magnets. Alnico uses powder coating and
electroplating when required and NdFeB magnets often have Nickel, Zinc,
Lacquer, Epoxy or Parylene as a protective coating.
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COMPARITIVE COSTS
Shape, tolerances and quantity will influence the prices of individual
magnets but the most significant effect is the cost of the basic raw
material.
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Ferrite (anisotropic)
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Low(x1)
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Alnico (anisotropic Alcomax III)
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Medium (x5)
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Samarium Cobalt 2:17)
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Very High(x20)
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Neodymium-Iron-Boron (N38H)
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High (x10)
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Tooling
is sometime necessary for new sizes and for volume production and
fixtures are sometime required for close tolerance machining.
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MAGNETIC RULES
- Flux lines always follow the paths of least resistance or in magnetic terms, path of greatest permanence (lowest reluctance).
- Flux lines repel each other if their direction of flow is the same and can never cross.
- Flux lines will always follow the shortest path through any medium
- Flux lines will normally always move in curved paths
- Flux lines always leave and enter the surfaces of ferromagnetic materials at right angles
- All
Ferromagnetic materials have limited ability to carry flux. When they
have reached their limit (saturated) then they behave as if they were
not there, like an air gap or similar.
- Flux lines will always travel from the nearest north pole to the nearest south pole, in a path that forms a closed loop.
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SOME USEFUL DESIGN ADVICE1. Stronger is not necessarily better
There are many factors to consider in magnetic design, Flux strength is only one of them.
2. Using a steel pole piece can often improve a magnets performance.
Sometimes it is useful to use a steel pole piece to help divert the flux to a more useful part of the magnetic circuit.
3. Always be aware of the working temperature of your application
Temperature is the biggest threat to magnetic stability, so always consider it as part of your design and your material/grade choice.
4. For holding/attracting applications, two poles are better than one.
But remember the flux will not travel as far, so keep the air gap between the magnet and what you want to attract as small as possible.
5. It is difficult to focus flux lines when using Rare Earth Magnets.
The use of steel poles in this instance is generally not effective.
6. The best test for a magnetic device is to replicate the application.
As there is not a simple single test which tells you all about a magnet, then it is often best to recreate the work the magnet will see in its application and include this somewhere in your testing procedure.
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TYPICAL MAGNETIC USES & APPLICATIONS
Permanent magnets are used in a wide variety application in all
industries but they can all be classified into one of the sections
below:-
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Conversion of Electrical Energy to Physical Motion
Actuators, speakers, motors, meters and other instrumentation.
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Conversion of Physical Motion into Electrical Energy
Generators, microphones and sensors.
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Producing Mechanical Energy
Holding, lifting, attracting, repelling, conveying, driving & separating
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Controlling Fields
Annealing, plasma control, sputtering, focusing & NMR.
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Mechanical to Heat
Eddie Current and Hysteresis drives
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